Additive-controlled chemoselective inter-/intramolecular hydroamination via electrochemical PCET process

Additive-controlled chemoselective inter-/intramolecular hydroamination via electrochemical PCET process

Electrochemically generated amidyl radical species produced distinct inter- or intramolecular hydroamination reaction products via a proton-coupled electron transfer (PCET) mechanism. Cyclic voltammetry (CV) analysis indicated that the chemoselectivity was derived from the size of the hydrogen bond...

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Bibliographic Details
Main Authors: Kazuhiro Okamoto, Naoki Shida, Mahito Atobe
Format: Article
Language:English
Published: Beilstein-Institut 2024-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
amidyl radical
cyclic voltammetry
electrosynthesis
hydroamination
proton coupled electron transfer
Online Access:https://doi.org/10.3762/bjoc.20.27

Internet

https://doi.org/10.3762/bjoc.20.27

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