Synthesis and crystal structure of a bench-stable pyridinium ketene hemiaminal: 1-(1-ethoxyethenyl)-2-[methyl(phenyl)amino]pyridin-1-ium trifluoromethanesulfonate

Synthesis and crystal structure of a bench-stable pyridinium ketene hemiaminal: 1-(1-ethoxyethenyl)-2-[methyl(phenyl)amino]pyridin-1-ium trifluoromethanesulfonate

The novel bench-stable N-quaternized ketene N,O-acetal, C16H19N2O+·CF3O3S−, was synthesized and its structure determined. The title compound is a rare example of a pyridinium ketene hemiaminal for which a crystal structure has been determined, joining the 2-chloro-1-(1-ethyoxyethenyl)pyridin-1-ium t...

Full description

Bibliographic Details
Main Authors: Zoe A. Krevlin, Isabella C. Bote, Maria Christina F. Crespo, Christie C. Lam, Colin D. McMillen, Max M. Majireck
Format: Article
Language:English
Published: International Union of Crystallography 2023-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
ketene hemiaminal
n-quaternized ketene n,o-acetal
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989023005741

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989023005741

Similar Items