Uncovering a reconstructive solid–solid phase transition in a metal–organic framework

Uncovering a reconstructive solid–solid phase transition in a metal–organic framework

A nanoporous three-dimensional metal–organic framework (MOF), ZnPurBr undergoes a transition to a previously unreported high-temperature phase, ZnPurBr-ht. The transition, which proceeds without mass loss, is uncovered through the use of differential scanning calorimetry (DSC). The new crystal struc...

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Bibliographic Details
Main Authors: L. Longley, N. Li, F. Wei, T. D. Bennett
Format: Article
Language:English
Published: The Royal Society 2017-01-01
Series:Royal Society Open Science
Subjects:
metal–organic framework
phase transition
x-ray
porous material
Online Access:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171355

Internet

https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171355

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