Sterol synthesis : chemical synthesis of 3 beta-hydroxy-5 alpha-cholest-7-ene-9 alpha-carbonitrile.
3 beta-Hydroxy-5 alpha-cholest-7-ene-9 alpha-carbonitrile was obtained via hydrocyanation of 3 beta-acetoxy-5 alpha-cholest-8-en-7-one by diethylaluminum cyanide. The resulting 9 alpha-cyano-7-ketone was reduced with sodium borohydride to 7 alpha-hydroxy-compound. These compounds were characterized...
| Váldodahkkit: | , |
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| Materiálatiipa: | Artihkal |
| Giella: | English |
| Almmustuhtton: |
Elsevier
1981-02-01
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| Ráidu: | Journal of Lipid Research |
| Liŋkkat: | http://www.sciencedirect.com/science/article/pii/S0022227520353797 |