Unexpected Formation of the Iodobismuthate Salt (C<sub>14</sub>H<sub>15</sub>S<sub>2</sub>N<sub>2</sub>)<sub>2</sub>(C<sub>9</sub>H<sub>10</sub>SN)<sub>2</sub>[Bi<sub>4</sub>I<sub>16</sub>] upon Reaction of the Unsaturated Ligand <i>Z</i>-PySCH<sub>2</sub>CH=CHCH<sub>2</sub>SPy with BiI<sub>3</sub>

Unexpected Formation of the Iodobismuthate Salt (C<sub>14</sub>H<sub>15</sub>S<sub>2</sub>N<sub>2</sub>)<sub>2</sub>(C<sub>9</sub>H<sub>10</sub>SN)<sub>2</sub>[Bi<sub>4</sub>I<sub>16</sub>] upon Reaction of the Unsaturated Ligand <i>Z</i>-PySCH<sub>2</sub>CH=CHCH<sub>2</sub>SPy with BiI<sub>3</sub>

The olefinic dithioether (<i>Z</i>)-1,4-bis(pyridin-2-ylthio)but-2-ene <i>Z</i>-PyS(CH<sub>2</sub>CH=CHCH<sub>2</sub>)SPy (<b>L</b>) was prepared by the treatment of <i>cis</i>-ClCH<sub>2</sub>CH=CHCH<sub>2<...

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Bibliographic Details
Main Authors: Marwa Essid, Chakib Hrizi, Salah Ammar, Abderrahim Khatyr, Michael Knorr, Annika Schmidt, Carsten Strohmann
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Molbank
Subjects:
bismuth triiodide
olefinic dithioether
crystal structure
Hirshfeld analysis
Online Access:https://www.mdpi.com/1422-8599/2024/1/M1755

Internet

https://www.mdpi.com/1422-8599/2024/1/M1755

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