Photochemical diazidation of alkenes enabled by ligand-to-metal charge transfer and radical ligand transfer

The difunctionalization of alkenes allows for efficient construction of molecular complexity. Combining Ligand-to-Metal Charge transfer (LMCT) and Radical Ligand Transfer (RLT), the authors show a photochemical diazidation using iron salts, allowing rapid preparation of vicinal diamines and other pr...

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Bibliographic Details
Main Authors: Kang-Jie Bian, Shih-Chieh Kao, David Nemoto, Xiao-Wei Chen, Julian G. West
Format: Article
Language:English
Published: Nature Portfolio 2022-12-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-35560-3