1,4,6,10-Tetraazaadamantanes (TAADs) with N-amino groups: synthesis and formation of boron chelates and host–guest complexes

1,4,6,10-Tetraazaadamantanes (TAADs) with N-amino groups: synthesis and formation of boron chelates and host–guest complexes

A synthetic route to 1,4,6,10-tetraazaadamantanes (TAADs) bearing free and protected amino groups at the bridge N-atoms has been developed via intramolecular cyclotrimerization of C=N units in the corresponding tris(hydrazonoalkyl)amines. In a similar fashion, unsymmetrically substituted TAADs havin...

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Bibliographic Details
Main Authors: Artem N. Semakin, Ivan S. Golovanov, Yulia V. Nelyubina, Alexey Yu. Sukhorukov
Format: Article
Language:English
Published: Beilstein-Institut 2022-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
azaadamantanes
cyclotrimerization
hydrazones
inclusion complexes
molecular recognition
Online Access:https://doi.org/10.3762/bjoc.18.148

Internet

https://doi.org/10.3762/bjoc.18.148

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