Bis(dimethylamido-κN)bis[2-(pyrrol-2-ylmethyleneamino)-2′-methoxy-6,6′-dimethyl-1,1′-biphenyl-κ2N,N′]vanadium(IV) toluene monosolvate

Bis(dimethylamido-κN)bis[2-(pyrrol-2-ylmethyleneamino)-2′-methoxy-6,6′-dimethyl-1,1′-biphenyl-κ2N,N′]vanadium(IV) toluene monosolvate

Reaction of the Schiff base ligand (R)-2-(pyrrol-2-ylmethyleneamino)-2′-methoxy-6,6′-dimethyl-1,1′-biphenyl with tetrakis(dimethylamido)vanadium in toluene gives the mononuclear VIV title complex, [V(C2H6N)2(C20H19N2O)2]·C7H8, which was isolated as red crystals. The VIV cation is coordinated by two...

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Bibliographic Details
Main Authors: Qiuwen Wang, Yihan Xiong, Xuebin Deng
Format: Article
Language:English
Published: International Union of Crystallography 2016-09-01
Series:IUCrData
Subjects:
crystal structure
vanadium(IV) complex
2-amino-2′-methoxy-6,6′-dimethyl-1,1′-biphenyl
Schiff base ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616014218

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http://scripts.iucr.org/cgi-bin/paper?S2414314616014218

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