Mechanistic insights into CO2 conversion chemistry of copper bis-(terpyridine) molecular electrocatalyst using accessible operando spectrochemistry

Transition metal complexes are potential low-cost electrocatalysts for CO2 reduction. Here, using accessible spectrochemistry, the authors observe an intriguing baton relay-like mechanism of active site transfer during CO2 reduction to CO on a carbon-supported copper bis-(terpyridine) complex.

Bibliographic Details
Main Authors: Huihui Zhang, Chang Xu, Xiaowen Zhan, Yu Yu, Kaifu Zhang, Qiquan Luo, Shan Gao, Jinlong Yang, Yi Xie
Format: Article
Language:English
Published: Nature Portfolio 2022-10-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-33689-9