Bonding Schemes for Polar Intermetallics through Molecular Orbital Models: Ca-Supported Pt–Pt Bonds in Ca10Pt7Si3

Exploratory synthesis in the area of polar intermetallics has yielded a rich variety of structures that offer clues into the transition in bonding between Zintl and Hume-Rothery phases. In this article, we present a bonding analysis of one such compound, Ca10Pt7Si3, whose large Ca content offers the...

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Bibliographic Details
Main Authors: Sven Lidin, Siméon Ponou, Isa Doverbratt, Daniel C. Fredrickson
Format: Article
Language:English
Published: MDPI AG 2013-09-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/3/3/504