Unusual highly diastereoselective Rh(II)-catalyzed dimerization of 3-diazo-2-arylidenesuccinimides provides access to a new dibenzazulene scaffold

Unusual highly diastereoselective Rh(II)-catalyzed dimerization of 3-diazo-2-arylidenesuccinimides provides access to a new dibenzazulene scaffold

Formation of unusual unsymmetrical dimers or/and indenes via Rh2(esp)2-catalyzed decomposition of 3-diazo-2-arylidenesuccinimides has been investigated. The reaction proceeded under mild conditions, and its result was shown to strongly depend on the nature of the substituents in the diazo substrate....

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Bibliographic Details
Main Authors: Anastasia Vepreva, Alexander S. Bunev, Andrey Yu. Kudinov, Grigory Kantin, Mikhail Krasavin, Dmitry Dar’in
Format: Article
Language:English
Published: Beilstein-Institut 2022-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
diazo arylidene succinimides
dibenzoazulenodipyrroles
indenopyrroles
rh2(esp)2-catalyzed decomposition
unsymmetrical dimers
Online Access:https://doi.org/10.3762/bjoc.18.55

Internet

https://doi.org/10.3762/bjoc.18.55

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