Non-Selective Dimerization of Vinyl Silanes by the Putative (Phenanthroline)PdMe Cation to 1,4-Bis(trialkoxysilyl)butenes

Activation of the dialkylpalladium complex (phen)Pd(CH3)2 (phen = 1,10-phenanthroline) with B(C6F5)3 affords a competent catalyst for the dimerization of vinyl silanes. All organic products of the catalytic dimerization of trialkoxyvinylsilanes were characterized by in situ NMR spectroscopy and GC&a...

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Bibliographic Details
Main Authors: Sandun Perera, Michael Findlater
Format: Article
Language:English
Published: MDPI AG 2018-09-01
Series:Inorganics
Subjects:
Online Access:http://www.mdpi.com/2304-6740/6/4/102