Charge State Effect of High Energy Ions on Material Modification in the Electronic Stopping Region

It has been observed that modifications of non-metallic solids such as sputtering and surface morphology are induced by electronic excitation under high-energy ion impact and that these modifications depend on the charge of incident ions (charge-state effect or incident-charge effect). A simple mode...

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Main Authors: Noriaki Matsunami, Masao Sataka, Satoru Okayasu, Bun Tsuchiya
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Atoms
Subjects:
Online Access:https://www.mdpi.com/2218-2004/9/3/36
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author Noriaki Matsunami
Masao Sataka
Satoru Okayasu
Bun Tsuchiya
author_facet Noriaki Matsunami
Masao Sataka
Satoru Okayasu
Bun Tsuchiya
author_sort Noriaki Matsunami
collection DOAJ
description It has been observed that modifications of non-metallic solids such as sputtering and surface morphology are induced by electronic excitation under high-energy ion impact and that these modifications depend on the charge of incident ions (charge-state effect or incident-charge effect). A simple model is described, consisting of an approximation to the mean-charge-evolution by saturation curves and the charge-dependent electronic stopping power, for the evaluation of the relative yield (e.g., electronic sputtering yield) of the non-equilibrium charge incidence over that of the equilibrium-charge incidence. It is found that the present model reasonably explains the charge state effect on the film thickness dependence of lattice disordering of WO<sub>3</sub>. On the other hand, the model appears to be inadequate to explain the charge-state effect on the electronic sputtering of WO<sub>3</sub> and LiF. Brief descriptions are given for the charge-state effect on the electronic sputtering of SiO<sub>2</sub>, UO<sub>2</sub> and UF<sub>4</sub>, and surface morphology modification of poly-methyl-methacrylate (PMMA), mica and tetrahedral amorphous carbon (ta-C).
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spelling doaj.art-aabbebd4c3ca49c2bc223c0c8b3356c62023-11-22T01:28:38ZengMDPI AGAtoms2218-20042021-06-01933610.3390/atoms9030036Charge State Effect of High Energy Ions on Material Modification in the Electronic Stopping RegionNoriaki Matsunami0Masao Sataka1Satoru Okayasu2Bun Tsuchiya3Faculty of Science and Technology, Meijo University, Nagoya 468-8502, JapanJapan Atomic Energy Agency (JAEA), Tokai 319-1195, JapanJapan Atomic Energy Agency (JAEA), Tokai 319-1195, JapanFaculty of Science and Technology, Meijo University, Nagoya 468-8502, JapanIt has been observed that modifications of non-metallic solids such as sputtering and surface morphology are induced by electronic excitation under high-energy ion impact and that these modifications depend on the charge of incident ions (charge-state effect or incident-charge effect). A simple model is described, consisting of an approximation to the mean-charge-evolution by saturation curves and the charge-dependent electronic stopping power, for the evaluation of the relative yield (e.g., electronic sputtering yield) of the non-equilibrium charge incidence over that of the equilibrium-charge incidence. It is found that the present model reasonably explains the charge state effect on the film thickness dependence of lattice disordering of WO<sub>3</sub>. On the other hand, the model appears to be inadequate to explain the charge-state effect on the electronic sputtering of WO<sub>3</sub> and LiF. Brief descriptions are given for the charge-state effect on the electronic sputtering of SiO<sub>2</sub>, UO<sub>2</sub> and UF<sub>4</sub>, and surface morphology modification of poly-methyl-methacrylate (PMMA), mica and tetrahedral amorphous carbon (ta-C).https://www.mdpi.com/2218-2004/9/3/36charge-state effectelectronic excitation effecthigh-energy ionnon-metallic solidmean-charge evolutionsputtering
spellingShingle Noriaki Matsunami
Masao Sataka
Satoru Okayasu
Bun Tsuchiya
Charge State Effect of High Energy Ions on Material Modification in the Electronic Stopping Region
Atoms
charge-state effect
electronic excitation effect
high-energy ion
non-metallic solid
mean-charge evolution
sputtering
title Charge State Effect of High Energy Ions on Material Modification in the Electronic Stopping Region
title_full Charge State Effect of High Energy Ions on Material Modification in the Electronic Stopping Region
title_fullStr Charge State Effect of High Energy Ions on Material Modification in the Electronic Stopping Region
title_full_unstemmed Charge State Effect of High Energy Ions on Material Modification in the Electronic Stopping Region
title_short Charge State Effect of High Energy Ions on Material Modification in the Electronic Stopping Region
title_sort charge state effect of high energy ions on material modification in the electronic stopping region
topic charge-state effect
electronic excitation effect
high-energy ion
non-metallic solid
mean-charge evolution
sputtering
url https://www.mdpi.com/2218-2004/9/3/36
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AT masaosataka chargestateeffectofhighenergyionsonmaterialmodificationintheelectronicstoppingregion
AT satoruokayasu chargestateeffectofhighenergyionsonmaterialmodificationintheelectronicstoppingregion
AT buntsuchiya chargestateeffectofhighenergyionsonmaterialmodificationintheelectronicstoppingregion