The Co-N bond cleavage in the adenosyncobalamin cofactor in advance to glutamate mutase and methylmalonyl-CoA mutase processes
The in vivo experiments show that the adenosylcobalamin cofactor in glutamate mutase and methylmalonyl-CoA mutase processes lose its dimethylbenzimidazole axial ligand before starting the enzymatic processes. Complete active space self-consistent field geometry optimization of the vitamin B12 active...
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Format: | Article |
Jezik: | English |
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Academy of Sciences of Moldova, Institute of Chemistry
2023-12-01
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Serija: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
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Online dostop: |
http://cjm.ichem.md/the-co-n-bond-cleavage-in-the-adenosyncobalamin-cofactor-in-advance-to-glutamate-mutase-and-methylmalonyl-coa-mutase-processes
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