The Co-N bond cleavage in the adenosyncobalamin cofactor in advance to glutamate mutase and methylmalonyl-CoA mutase processes

The Co-N bond cleavage in the adenosyncobalamin cofactor in advance to glutamate mutase and methylmalonyl-CoA mutase processes

The in vivo experiments show that the adenosylcobalamin cofactor in glutamate mutase and methylmalonyl-CoA mutase processes lose its dimethylbenzimidazole axial ligand before starting the enzymatic processes. Complete active space self-consistent field geometry optimization of the vitamin B12 active...

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Hlavní autor: Tudor Spataru
Médium: Článek
Jazyk:English
Vydáno: Academy of Sciences of Moldova, Institute of Chemistry 2023-12-01
Edice:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Témata:
dglutamate mutase
methylmalonyl-coa mutase
adenosylcobalamin cofactor
vitamin b12
pseudo-jahn-teller effect
On-line přístup: http://cjm.ichem.md/the-co-n-bond-cleavage-in-the-adenosyncobalamin-cofactor-in-advance-to-glutamate-mutase-and-methylmalonyl-coa-mutase-processes

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http://cjm.ichem.md/the-co-n-bond-cleavage-in-the-adenosyncobalamin-cofactor-in-advance-to-glutamate-mutase-and-methylmalonyl-coa-mutase-processes

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