Crystal structure of a dinuclear CoII complex with bridging fluoride ligands: di-μ-fluorido-bis{tris[(6-methylpyridin-2-yl)methyl]amine}dicobalt(II) bis(tetrafluoridoborate)

Crystal structure of a dinuclear CoII complex with bridging fluoride ligands: di-μ-fluorido-bis{tris[(6-methylpyridin-2-yl)methyl]amine}dicobalt(II) bis(tetrafluoridoborate)

Reaction of Co(BF4)2·6H2O with tris[(6-methylpyridin-2-yl)methyl]amiine in methanol results in a fluoride abstraction from BF4−, yielding the unexpected title compound, [Co2F2(C21H24N4)2](BF4)2. The complex cation consists of two inversion-related [Co(C21H24N4)]2+ moieties bridged by a pair of fluor...

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Bibliographic Details
Main Authors: Masataka Inomata, Yusaku Suenaga
Format: Article
Language:English
Published: International Union of Crystallography 2014-11-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
dinuclear cobalt complex
fluoride bridge
high-spin CoII complex
tripodal ligand
C—H...F hydrogen bonds
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814021631

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http://scripts.iucr.org/cgi-bin/paper?S1600536814021631

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