Cobalt-Catalyzed Methoxycarbonylation of Substituted Dichlorobenzenes as an Example of a Facile Radical Anion Nucleophilic Substitution in Chloroarenes

Cobalt-Catalyzed Methoxycarbonylation of Substituted Dichlorobenzenes as an Example of a Facile Radical Anion Nucleophilic Substitution in Chloroarenes

A thorough mechanistic study on cobalt-catalysed direct methoxycarbonylation reactions of chlorobenzenes in the presence of methyl oxirane on a wide range of substrates, including poly- and monochloro derivatives with multiple substituents, is reported. The results demonstrate that the reaction is p...

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Bibliographic Details
Main Authors: Tatyana S. Khaibulova, Irina A. Boyarskaya, Evgeny Larionov, Vadim P. Boyarskiy
Format: Article
Language:English
Published: MDPI AG 2014-05-01
Series:Molecules
Subjects:
cobalt-catalysed methoxycarbonylation
aryl chlorides
synthesis of substituted benzoic acids
radical anion nucleophilic substitution
ortho-effect
Online Access:http://www.mdpi.com/1420-3049/19/5/5876

Internet

http://www.mdpi.com/1420-3049/19/5/5876

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