(η4-1,5-Cyclooctadiene)[(R)-(+)-5,5′,6,6′,7,7′,8,8′-octahydro-2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl-κ2P,P′]rhodium(I) tetrafluoroborate 0.72-pentane 0.56-methanol solvate

(η4-1,5-Cyclooctadiene)[(R)-(+)-5,5′,6,6′,7,7′,8,8′-octahydro-2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl-κ2P,P′]rhodium(I) tetrafluoroborate 0.72-pentane 0.56-methanol solvate

The title compound, [Rh(C8H12)(C44H20P2)]BF4·0.72C5H12·0.56·CH4O, crystallizes in the Sohncke space group P21. The RhI centre is coordinated by a H8-BINAP 5,5′,6,6′,7,7′,8,8′-octahydro-2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl ligand and by a bidentate η2,η2-coordinated cod (cycloocta-1,5-diene)...

Full description

Bibliographic Details
Main Authors: Cornelia Pribbenow, Julia Rueger, Hans-Joachim Drexler, Detlef Heller
Format: Article
Language:English
Published: International Union of Crystallography 2017-09-01
Series:IUCrData
Subjects:
crystal structure
rhodium complex
hydrogenation
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314617012408

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314617012408

Similar Items