(η4-1,5-Cyclooctadiene)[(R)-(+)-5,5′,6,6′,7,7′,8,8′-octahydro-2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl-κ2P,P′]rhodium(I) tetrafluoroborate 0.72-pentane 0.56-methanol solvate

(η4-1,5-Cyclooctadiene)[(R)-(+)-5,5′,6,6′,7,7′,8,8′-octahydro-2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl-κ2P,P′]rhodium(I) tetrafluoroborate 0.72-pentane 0.56-methanol solvate

The title compound, [Rh(C8H12)(C44H20P2)]BF4·0.72C5H12·0.56·CH4O, crystallizes in the Sohncke space group P21. The RhI centre is coordinated by a H8-BINAP 5,5′,6,6′,7,7′,8,8′-octahydro-2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl ligand and by a bidentate η2,η2-coordinated cod (cycloocta-1,5-diene)...

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Bibliographic Details
Main Authors:	Cornelia Pribbenow, Julia Rueger, Hans-Joachim Drexler, Detlef Heller
Format:	Article
Language:	English
Published:	International Union of Crystallography 2017-09-01
Series:	IUCrData
Subjects:	crystal structure rhodium complex hydrogenation
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2414314617012408

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