The Smoluchowski Ensemble—Statistical Mechanics of Aggregation

We present a rigorous thermodynamic treatment of irreversible binary aggregation. We construct the Smoluchowski ensemble as the set of discrete finite distributions that are reached in fixed number of merging events and define a probability measure on this ensemble, such that the mean distribution i...

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Bibliographic Details
Main Author: Themis Matsoukas
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/22/10/1181