Oxidation behavior of Al2O3 added reaction-sintered SiC ceramics in wet oxygen environment at 1300°C

The oxidation behavior of reaction-bonded SiC ceramics with Al2O3 was investigated at 1300°C for exposure duration up to 100 h under water vapor environment. Results show that Al2O3 is enriched on the oxidation surface, reducing the volatilization of the oxide layer and preventing the reduction of m...

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Main Authors: Qingliang Shan, Jianbao Hu, Jinshan Yang, Yanmei Kan, Haijun Zhou, Guangxiang Zhu, Yudong Xue, Shaoming Dong
Format: Article
Language:English
Published: Taylor & Francis Group 2018-07-01
Series:Journal of Asian Ceramic Societies
Subjects:
Online Access:http://dx.doi.org/10.1080/21870764.2018.1504731
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author Qingliang Shan
Jianbao Hu
Jinshan Yang
Yanmei Kan
Haijun Zhou
Guangxiang Zhu
Yudong Xue
Shaoming Dong
author_facet Qingliang Shan
Jianbao Hu
Jinshan Yang
Yanmei Kan
Haijun Zhou
Guangxiang Zhu
Yudong Xue
Shaoming Dong
author_sort Qingliang Shan
collection DOAJ
description The oxidation behavior of reaction-bonded SiC ceramics with Al2O3 was investigated at 1300°C for exposure duration up to 100 h under water vapor environment. Results show that Al2O3 is enriched on the oxidation surface, reducing the volatilization of the oxide layer and preventing the reduction of macroscopic size. Raman spectra results further testified that Al2O3 obviously improves the stability of glass structure and reduces the generation of non-bridged oxygen atoms (Si–O–H), which results in a lower reaction activity with steam of the aluminosilicate melt, therefore, significantly improving the oxidation resistance of SiC in O2/H2O atmosphere.
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spelling doaj.art-ad532ac54ed24092a24616fd3f283fbb2022-12-21T22:27:40ZengTaylor & Francis GroupJournal of Asian Ceramic Societies2187-07642018-07-016325426110.1080/21870764.2018.15047311504731Oxidation behavior of Al2O3 added reaction-sintered SiC ceramics in wet oxygen environment at 1300°CQingliang Shan0Jianbao Hu1Jinshan Yang2Yanmei Kan3Haijun Zhou4Guangxiang Zhu5Yudong Xue6Shaoming Dong7Shanghai Institute of Ceramics, Chinese Academy of SciencesShanghai Institute of Ceramics, Chinese Academy of SciencesShanghai Institute of Ceramics, Chinese Academy of SciencesShanghai Institute of Ceramics, Chinese Academy of SciencesShanghai Institute of Ceramics, Chinese Academy of SciencesShanghai Institute of Ceramics, Chinese Academy of SciencesShanghai Institute of Ceramics, Chinese Academy of SciencesShanghai Institute of Ceramics, Chinese Academy of SciencesThe oxidation behavior of reaction-bonded SiC ceramics with Al2O3 was investigated at 1300°C for exposure duration up to 100 h under water vapor environment. Results show that Al2O3 is enriched on the oxidation surface, reducing the volatilization of the oxide layer and preventing the reduction of macroscopic size. Raman spectra results further testified that Al2O3 obviously improves the stability of glass structure and reduces the generation of non-bridged oxygen atoms (Si–O–H), which results in a lower reaction activity with steam of the aluminosilicate melt, therefore, significantly improving the oxidation resistance of SiC in O2/H2O atmosphere.http://dx.doi.org/10.1080/21870764.2018.1504731SiC ceramicswater vaporaluminosilicates
spellingShingle Qingliang Shan
Jianbao Hu
Jinshan Yang
Yanmei Kan
Haijun Zhou
Guangxiang Zhu
Yudong Xue
Shaoming Dong
Oxidation behavior of Al2O3 added reaction-sintered SiC ceramics in wet oxygen environment at 1300°C
Journal of Asian Ceramic Societies
SiC ceramics
water vapor
aluminosilicates
title Oxidation behavior of Al2O3 added reaction-sintered SiC ceramics in wet oxygen environment at 1300°C
title_full Oxidation behavior of Al2O3 added reaction-sintered SiC ceramics in wet oxygen environment at 1300°C
title_fullStr Oxidation behavior of Al2O3 added reaction-sintered SiC ceramics in wet oxygen environment at 1300°C
title_full_unstemmed Oxidation behavior of Al2O3 added reaction-sintered SiC ceramics in wet oxygen environment at 1300°C
title_short Oxidation behavior of Al2O3 added reaction-sintered SiC ceramics in wet oxygen environment at 1300°C
title_sort oxidation behavior of al2o3 added reaction sintered sic ceramics in wet oxygen environment at 1300°c
topic SiC ceramics
water vapor
aluminosilicates
url http://dx.doi.org/10.1080/21870764.2018.1504731
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