Sulfur-mediated chalcogen versus hydrogen bonds in proteins: a see-saw effect in the conformational space
Divalent sulfur (S) forms a chalcogen bond (Ch-bond) via its σ-holes and a hydrogen bond (H-bond) via its lone pairs. The relevance of these interactions and their interplay for protein structure and function is unclear. Based on the analyses of the crystal structures of small organic/organometallic...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
Cambridge University Press
2023-01-01
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Series: | QRB Discovery |
Subjects: | |
Online Access: | https://www.cambridge.org/core/product/identifier/S2633289223000030/type/journal_article |