A Computational Chemistry Investigation of the Influence of Steric Bulk of Dithiocarbamato-Bound Organic Substituents upon Spodium Bonding in Three Homoleptic Mercury(II) Bis(N,N-dialkyldithiocarbamato) Compounds for Alkyl = Ethyl, Isobutyl, and Cyclohexyl

A Computational Chemistry Investigation of the Influence of Steric Bulk of Dithiocarbamato-Bound Organic Substituents upon Spodium Bonding in Three Homoleptic Mercury(II) Bis(N,N-dialkyldithiocarbamato) Compounds for Alkyl = Ethyl, Isobutyl, and Cyclohexyl

Three homoleptic Hg(S<sub>2</sub>CNR<sub>2</sub>)<sub>2</sub>, for R = ethyl (<b>1</b>), isobutyl (<b>2</b>), and cyclohexyl (<b>3</b>), compounds apparently exhibit a steric-dependent supramolecular association in their crystal...

Full description

Bibliographic Details
Main Authors: Rosa M. Gomila, Edward R. T. Tiekink, Antonio Frontera
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Inorganics
Subjects:
mercury
dithiocarbamate
steric effects
noncovalent interactions
spodium bonding
molecular electrostatic potential (MEP)
Online Access:https://www.mdpi.com/2304-6740/11/12/468

Internet

https://www.mdpi.com/2304-6740/11/12/468

Similar Items