Towards Optimized Photoluminescent Copper(I) Phenanthroline-Functionalized Complexes: Control of the Photophysics by Symmetry-Breaking and Spin–Orbit Coupling

Towards Optimized Photoluminescent Copper(I) Phenanthroline-Functionalized Complexes: Control of the Photophysics by Symmetry-Breaking and Spin–Orbit Coupling

The electronic and structural alterations induced by the functionalization of the 1,10-phenanthroline (phen) ligand in [Cu(I) (phen-R<sub>2</sub>)<sub>2</sub>]<sup>+</sup> complexes (R=H, CH<sub>3</sub>, <i>tertio</i>-butyl, alkyl-linkers)...

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Bibliographic Details
Main Authors: Christophe Gourlaouen, Chantal Daniel
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Materials
Subjects:
luminescence
TADF
copper(I) phenanthroline functionalization
density functional theory
nuclear relaxation
symmetry-breaking spin–orbit coupling
Online Access:https://www.mdpi.com/1996-1944/15/15/5222

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https://www.mdpi.com/1996-1944/15/15/5222

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