Novel Copper(II) Complexes with BIAN Ligands: Synthesis, Structure and Catalytic Properties of the Oxidation of Isopropylbenzene

Novel Copper(II) Complexes with BIAN Ligands: Synthesis, Structure and Catalytic Properties of the Oxidation of Isopropylbenzene

Two new isomeric complexes [CuBr<sub>2</sub>(R-bian)] (R = 4-Me-Ph (<b>1</b>), 2-Me-Ph (<b>2</b>)) were obtained by reacting copper(II) bromide with 1,2-bis[(2-methylphenyl)imino]acenaphthene ligands and characterized. The crystal structure of <b>2</b>...

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Bibliographic Details
Main Authors: Iakov S. Fomenko, Olga S. Koshcheeva, Nina I. Kuznetsova, Tatyana V. Larina, Marko I. Gongola, Medhanie Afewerki, Pavel A. Abramov, Alexander S. Novikov, Artem L. Gushchin
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Catalysts
Subjects:
copper complexes
BIAN ligands
redox-active ligands
oxidation
isopropylbenzene
Online Access:https://www.mdpi.com/2073-4344/13/5/849

Internet

https://www.mdpi.com/2073-4344/13/5/849

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