Kinetics and mechanism of the oxidation of polyhydric alcohols by dihydroxyditelluratoargentate(III) in alkaline medium

Kinetics and mechanism of the oxidation of polyhydric alcohols by dihydroxyditelluratoargentate(III) in alkaline medium

The kinetics of oxidation of 1,2-propanediol and 1,2,3-propanetriol by dihydroxyditelluratoargentate(III) (DDA) were studied spectrophotometrically between 298.2 K and 313.2 K in alkaline medium. The reaction rate showed first order dependence on DDA and 1 < nap < 2 order on the reductant. It...

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Bibliographic Details
Main Authors: JIN-HUAN SHAN, SHU-YING HUO, SHI-GANG SHEN, HAN-WEN SUN
Format: Article
Language:English
Published: Serbian Chemical Society 2005-04-01
Series:Journal of the Serbian Chemical Society
Subjects:
dihydroxyditelluratoargentate(III)
1
2-propanediol
2
3-propanetriol
redox reaction
kinetics and mechanism
Online Access:http://www.shd.org.yu/HtDocs/SHD/vol70/No4/JSCS_V70_No4-04.pdf

Internet

http://www.shd.org.yu/HtDocs/SHD/vol70/No4/JSCS_V70_No4-04.pdf

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