Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow

A copper-based photocatalyst, Cu(tmp)(BINAP)BF4, was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and ca...

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Bibliographic Details
Main Authors: Clémentine Minozzi, Jean-Christophe Grenier-Petel, Shawn Parisien-Collette, Shawn K. Collins
Format: Article
Language:English
Published: Beilstein-Institut 2018-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.14.251