Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
A copper-based photocatalyst, Cu(tmp)(BINAP)BF4, was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and ca...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2018-10-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.14.251 |
| _version_ | 1818433130083647488 |
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| author | Clémentine Minozzi Jean-Christophe Grenier-Petel Shawn Parisien-Collette Shawn K. Collins |
| author_facet | Clémentine Minozzi Jean-Christophe Grenier-Petel Shawn Parisien-Collette Shawn K. Collins |
| author_sort | Clémentine Minozzi |
| collection | DOAJ |
| description | A copper-based photocatalyst, Cu(tmp)(BINAP)BF4, was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and carboxylic acids to their anhydrides. The protocol was also amendable and optimized under continuous flow conditions. |
| first_indexed | 2024-12-14T16:16:12Z |
| format | Article |
| id | doaj.art-b0735e1c41054d35b697a20b6fafd15a |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-14T16:16:12Z |
| publishDate | 2018-10-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-b0735e1c41054d35b697a20b6fafd15a2022-12-21T22:54:54ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972018-10-011412730273610.3762/bjoc.14.2511860-5397-14-251Photocatalyic Appel reaction enabled by copper-based complexes in continuous flowClémentine Minozzi0Jean-Christophe Grenier-Petel1Shawn Parisien-Collette2Shawn K. Collins3Department of Chemistry and Centre for Green Chemistry and Catalysis, Université de Montréal, CP 6128 Station Downtown, Montréal, Québec, H3C 3J7, CanadaDepartment of Chemistry and Centre for Green Chemistry and Catalysis, Université de Montréal, CP 6128 Station Downtown, Montréal, Québec, H3C 3J7, CanadaDepartment of Chemistry and Centre for Green Chemistry and Catalysis, Université de Montréal, CP 6128 Station Downtown, Montréal, Québec, H3C 3J7, CanadaDepartment of Chemistry and Centre for Green Chemistry and Catalysis, Université de Montréal, CP 6128 Station Downtown, Montréal, Québec, H3C 3J7, CanadaA copper-based photocatalyst, Cu(tmp)(BINAP)BF4, was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and carboxylic acids to their anhydrides. The protocol was also amendable and optimized under continuous flow conditions.https://doi.org/10.3762/bjoc.14.251Appelcontinuous flowcopperhalidesphotocatalysis |
| spellingShingle | Clémentine Minozzi Jean-Christophe Grenier-Petel Shawn Parisien-Collette Shawn K. Collins Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow Beilstein Journal of Organic Chemistry Appel continuous flow copper halides photocatalysis |
| title | Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow |
| title_full | Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow |
| title_fullStr | Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow |
| title_full_unstemmed | Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow |
| title_short | Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow |
| title_sort | photocatalyic appel reaction enabled by copper based complexes in continuous flow |
| topic | Appel continuous flow copper halides photocatalysis |
| url | https://doi.org/10.3762/bjoc.14.251 |
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