UV spectroscopic determination of the chlorine monoxide (ClO) ∕ chlorine peroxide (ClOOCl) thermal equilibrium constant

<p>The thermal equilibrium constant between the chlorine monoxide radical (ClO) and its dimer, chlorine peroxide (ClOOCl), was determined as a function of temperature between 228 and 301&thinsp;K in a discharge flow apparatus using broadband UV absorption spectroscopy. A third-law fit of t...

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Bibliographic Details
Main Authors: J. E. Klobas, D. M. Wilmouth
Format: Article
Language:English
Published: Copernicus Publications 2019-05-01
Series:Atmospheric Chemistry and Physics
Online Access:https://www.atmos-chem-phys.net/19/6205/2019/acp-19-6205-2019.pdf