Anion‐Bridged Dual Hydrogen Bond Enabled Concerted Addition of Phenol to Glycal

Anion‐Bridged Dual Hydrogen Bond Enabled Concerted Addition of Phenol to Glycal

Abstract A noncovalent organocatalytic concerted addition of phenol to glycal is developed for the stereoselective and regioselective construction of biologically important phenolic 2‐deoxyglycosides, featuring wide substrate tolerance. The method relies on an anion‐bridged dual hydrogen bond intera...

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Bibliographic Details
Main Authors: Qinbo Jiao, Zhenbo Guo, Mingwen Zheng, Wentao Lin, Yujie Liao, Weitao Yan, Tianfei Liu, Chunfa Xu
Format: Article
Language:English
Published: Wiley 2024-03-01
Series:Advanced Science
Subjects:
concerted addition
glycosylation
hydrogen bond
organocatalysis
phenolic glycoside
Online Access:https://doi.org/10.1002/advs.202308513

Internet

https://doi.org/10.1002/advs.202308513

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