Samarium Diiodide Acting on Acetone—Modeling Single Electron Transfer Energetics in Solution

Samarium Diiodide Acting on Acetone—Modeling Single Electron Transfer Energetics in Solution

Samarium diiodide is a versatile single electron transfer (SET) agent with various applications in organic chemistry. Lewis structures regularly insinuate the existence of a ketyl radical when samarium diiodide binds a carbonyl group. The study presented here investigates this electron transfer by t...

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Bibliographic Details
Main Authors: Luca Steiner, Andreas J. Achazi, Bess Vlaisavljevich, Pere Miro, Beate Paulus, Anne-Marie Kelterer
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Molecules
Subjects:
computational chemistry
lanthanoide chemistry
density functional theory
ketyl radical
HMPA influence
reduction potential
Online Access:https://www.mdpi.com/1420-3049/27/24/8673

Internet

https://www.mdpi.com/1420-3049/27/24/8673

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