Steps toward Rationalization of the Enantiomeric Excess of the Sakurai–Hosomi–Denmark Allylation Catalyzed by Biisoquinoline N,N’-Dioxides Using Computations

Steps toward Rationalization of the Enantiomeric Excess of the Sakurai–Hosomi–Denmark Allylation Catalyzed by Biisoquinoline N,N’-Dioxides Using Computations

Allylation reactions of aldehydes are chemical transformations of fundamental interest, as they give direct access to chiral homoallylic alcohols. In this work, we focus on the full computational characterization of the catalytic activity of substituted biisoquinoline-N,N’-dioxides for the allylatio...

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Bibliographic Details
Main Authors: Pierpaolo Morgante, Coty Deluca, Tegla E. Jones, Gregory J. Aldrich, Norito Takenaka, Roberto Peverati
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Catalysts
Subjects:
DFT
Lewis bases
organocatalysis
allyltrichlorosilane
Online Access:https://www.mdpi.com/2073-4344/11/12/1487

Internet

https://www.mdpi.com/2073-4344/11/12/1487

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