Redox-Switchable Behavior of Transition-Metal Complexes Supported by Amino-Decorated N-Heterocyclic Carbenes

Redox-Switchable Behavior of Transition-Metal Complexes Supported by Amino-Decorated N-Heterocyclic Carbenes

The coordination chemistry of the N-heterocyclic carbene ligand IMes<sup>(NMe2)2</sup>, derived from the well-known IMes ligand by substitution of the carbenic heterocycle with two dimethylamino groups, was investigated with d<sup>6</sup> [Mn(I), Fe(II)], d<sup>8</su...

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Bibliographic Details
Main Authors: Mirko Ruamps, Stéphanie Bastin, Lionel Rechignat, Alix Sournia-Saquet, Laure Vendier, Noël Lugan, Jean-Marie Mouesca, Dmitry A. Valyaev, Vincent Maurel, Vincent César
Format: Article
Language:English
Published: MDPI AG 2022-06-01
Series:Molecules
Subjects:
redox-active ligands
N-heterocyclic carbene
organometallic complexes
EPR spectroscopy
DFT calculations
Online Access:https://www.mdpi.com/1420-3049/27/12/3776

Internet

https://www.mdpi.com/1420-3049/27/12/3776

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