Electrogenerated base-promoted cyclopropanation using alkyl 2-chloroacetates

Electrogenerated base-promoted cyclopropanation using alkyl 2-chloroacetates

The electrochemical reduction conditions of the reaction of alkyl 2-chloroacetates in Bu4NBr/DMF using a divided cell equipped with Pt electrodes to produce the corresponding cyclopropane derivatives in moderate yields were discovered. The reaction conditions were optimized, the scope and limitation...

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Bibliographic Details
Main Authors: Kouichi Matsumoto, Yuta Hayashi, Kengo Hamasaki, Mizuki Matsuse, Hiyono Suzuki, Keiji Nishiwaki, Norihito Kawashita
Format: Article
Language:English
Published: Beilstein-Institut 2022-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
alkyl 2-chloroacetates
cyclopropane derivatives
divided cell
electro-reduction
Online Access:https://doi.org/10.3762/bjoc.18.114

Internet

https://doi.org/10.3762/bjoc.18.114

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