Synthesis of Catena-bis(μ-bromo)-(<i>O</i>-methyl-<i>N</i>-phenylthiocarbamate)-dicopper(I) and Its Reactivity towards PAr<sub>3</sub> (Ar = Ph, <i>p</i>-Tol)

Synthesis of Catena-bis(μ-bromo)-(<i>O</i>-methyl-<i>N</i>-phenylthiocarbamate)-dicopper(I) and Its Reactivity towards PAr<sub>3</sub> (Ar = Ph, <i>p</i>-Tol)

In order to investigate the coordination chemistry of <i>O</i>-alkyl <i>N</i>-aryl thiocarbamate ligands toward coinage metals, CuBr was reacted with one equivalent of MeOC(=S)N(H)Ph <b>L</b> in MeCN solution to afford the 1D-polymeric title compound [{Cu(<i>...

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Bibliographic Details
Main Authors: Wafa Arar, Lydie Viau, Isabelle Jourdain, Michael Knorr, Carsten Strohmann, Rebecca Scheel, Azaiez Ben Akacha
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Molbank
Subjects:
copper bromide
thiocarbamate
thione
crystal structure
hydrogen bonding
aryl phosphine
Online Access:https://www.mdpi.com/1422-8599/2023/2/M1655

Internet

https://www.mdpi.com/1422-8599/2023/2/M1655

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