Synthesis, crystal structure and Hirshfeld analysis of trans-bis(2-{1-[(6R,S)-3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl]ethylidene}-N-methylhydrazinecarbothioamidato-κ2N2,S)palladium(II) ethanol monosolvate

Synthesis, crystal structure and Hirshfeld analysis of trans-bis(2-{1-[(6R,S)-3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl]ethylidene}-N-methylhydrazinecarbothioamidato-κ2N2,S)palladium(II) ethanol monosolvate

The reaction between the (R,S)-fixolide 4-methylthiosemicarbazone and PdII chloride yielded the title compound, [Pd(C20H30N3S)2]·C2H6O {common name: trans-bis[(R,S)-fixolide 4-methylthiosemicarbazonato-κ2N2S]palladium(II) ethanol monosolvate}. The asymmetric unit of the title compound consists of on...

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Bibliographic Details
Main Authors: Ana Paula Lopes de Melo, Leandro Bresolin, Bárbara Tirloni, Renan Lira de Farias, Adriano Bof de Oliveira
Format: Article
Language:English
Published: International Union of Crystallography 2023-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
palladium(ii) thiosemicarbazone-complex
fixolide 4-methylthiosemicarbazone
hirshfeld surface analysis
anagostic interaction
hydrogen-bonded macrocyclic environment
hydrogen-bonded ribbons
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989023009908

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http://scripts.iucr.org/cgi-bin/paper?S2056989023009908

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