Effect of Activator and Outgoing Ligand Nature on the Catalytic Behavior of Bis(phenoxy-imine) Ti(IV) Complexes in the Polymerization of Ethylene and Its Copolymerization with Higher Olefins

Effect of Activator and Outgoing Ligand Nature on the Catalytic Behavior of Bis(phenoxy-imine) Ti(IV) Complexes in the Polymerization of Ethylene and Its Copolymerization with Higher Olefins

A series of bis(phenoxy-imine) (FI) titanium(IV) and zirconium(IV) complexes have been synthesized. The effect of the nature of the activator (MAO, combinations Et<sub>n</sub>AlCl<sub>3-n</sub> + Bu<sub>2</sub>Mg and iBu<sub>3</sub>Al + [Ph<sub>3...

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Main Authors: Svetlana Ch. Gagieva, Kasim F. Magomedov, Vladislav A. Tuskaev, Vyacheslav S. Bogdanov, Dmitrii A. Kurmaev, Evgenii K. Golubev, Gleb L. Denisov, Galina G. Nikiforova, Maria D. Evseeva, Daniele Saracheno, Mikhail I. Buzin, Pavel B. Dzhevakov, Viktor I. Privalov, Boris M. Bulychev
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Polymers
Subjects:
FI catalysts
titanium(IV)
zirconium(IV)
polymerization
copolymerization
ultra-high molecular weight polyethylene
Online Access:https://www.mdpi.com/2073-4360/14/20/4397

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https://www.mdpi.com/2073-4360/14/20/4397

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