Crystal structure of bis(μ2-methanolato-κO:κO)hexamethylbis(μ2-triphenylacetato-κO:κO′)bis(μ2-triphenylacetato-κ2O,O′:κO)dialuminiumdilanthanum toluene tetrasolvate

Crystal structure of bis(μ2-methanolato-κO:κO)hexamethylbis(μ2-triphenylacetato-κO:κO′)bis(μ2-triphenylacetato-κ2O,O′:κO)dialuminiumdilanthanum toluene tetrasolvate

The title compound, [Al2La2(C20H15O2)4(CH3)6(CH3O)2]·4CH3C6H5 or [{La(Ph3CCOO)2(Me3AlOMe)}2]·4CH3C6H5, was formed in a reaction between lanthanum tris(tetramethylaluminate) and triphenylacetic acid (1:1) with unintended partial oxidation. The triphenylacetate ligand exhibits μ2-κ1O:κ1O′ bridging and...

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Bibliographic Details
Main Authors: Alexander A. Vinogradov, Dmitrii M. Roitershtein, Mikhail E. Minyaev, Konstantin A. Lyssenko, Ilya E. Nifant'ev
Format: Article
Language:English
Published: International Union of Crystallography 2018-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
lanthanum
aluminium
triphenylacetate
π-complex
coordination compound
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018015876

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989018015876

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