Pd-Catalyzed Amination in the Synthesis of a New Family of Macropolycyclic Compounds Comprising Diazacrown Ether Moieties

Pd-Catalyzed Amination in the Synthesis of a New Family of Macropolycyclic Compounds Comprising Diazacrown Ether Moieties

N,N'-bis(bromobenzyl) and N,N'-bis(halopyridinyl) derivatives of diaza-12-crown-4, diaza-15-crown-5 and diaza-18-crown-6 ethers were synthesized in high yields. The Pd-catalyzed macrocyclization reactions of these compounds were carried out using a variety of polyamines and oxadiamines we...

Full description

Bibliographic Details
Main Authors: Alexei A. Yakushev, Nataliya M. Chernichenko, Maxim V. Anokhin, Alexei D. Averin, Alexei K. Buryak, Franck Denat, Irina P. Beletskaya
Format: Article
Language:English
Published: MDPI AG 2014-01-01
Series:Molecules
Subjects:
diazacrown ethers
polyamines
Pd catalysis
amination
macropolycycles
Online Access:http://www.mdpi.com/1420-3049/19/1/940

Internet

http://www.mdpi.com/1420-3049/19/1/940

Similar Items