Transformation of Dialkyl-Substituted Alkynes under the Action of the TaCl<sub>5</sub>-Mg and NbCl<sub>5</sub>-Mg Reagent System

Transformation of Dialkyl-Substituted Alkynes under the Action of the TaCl<sub>5</sub>-Mg and NbCl<sub>5</sub>-Mg Reagent System

A regioselective method for the preparation of <i>p</i>-tolyl-substituted alkanes is presented based on the reaction of dialkyl-substituted alkynes with four equivalents of TaCl<sub>5</sub> or NbCl<sub>5</sub> in the presence of stoichiometric amounts of metallic...

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Bibliographic Details
Main Authors: Azat M. Gabdullin, Oleg S. Mozgovoj, Rita N. Kadikova, Ilfir R. Ramazanov, Usein M. Dzhemilev
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Chemistry Proceedings
Subjects:
alkynes
tantalum (V) chloride
niobium (V) chloride
metallic magnesium
toluene
Online Access:https://www.mdpi.com/2673-4583/8/1/52

Internet

https://www.mdpi.com/2673-4583/8/1/52

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