Reaction of quinaldine with 4,6-di(tert-butyl)-3-nitro-1,2-benzoquinone. Dependence of the outcome on the reaction conditions and a deeper insight into the mechanism

Reaction of quinaldine with 4,6-di(tert-butyl)-3-nitro-1,2-benzoquinone. Dependence of the outcome on the reaction conditions and a deeper insight into the mechanism

Condensation of quinaldine with 4,6-di (tert-butyl)-3-nitro-1,2-benzoquinone results in the formation of 5,7-di (tert-butyl)-2-(quinoline-2-yl)-1,3-tropolone, 5,7-di (tert-butyl)-4-nitro-2-(quinoline-2-yl)-1,3-tropolone, 3,3-dimethyl-2-(5-hydroxy-4-nitro-3-tert-butyl-6-quinoline-2-yl-pyridine-2-yl)b...

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Bibliographic Details
Main Authors: Tatyana A. Krasnikova, Yurii A. Sayapin, Inna O. Tupaeva, Eugeny A. Gusakov, Ilya V. Ozhogin, Anton V. Lisovin, Mikhail V. Nikogosov, Oleg P. Demidov, Duong Nghia Bang, Tran Dai Lam, Nguyen Thi Thu Trang, Alexander D. Dubonosov, Vladimir I. Minkin
Format: Article
Language:English
Published: Elsevier 2023-06-01
Series:Heliyon
Subjects:
4,6-Di(tert-butyl)-3-nitro-1,2-benzoquinone
o-Quinone ring expansion
Contraction of the o-quinone ring
1,3-Tropolones
DFT
X-ray spectroscopy
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844023041506

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