Enantio and Diastereoselective Addition of Phenylacetylene to Racemic α-chloroketones

Enantio and Diastereoselective Addition of Phenylacetylene to Racemic α-chloroketones

In this report, we have presented the first diastereoselective addition of phenylacetylene to chiral racemic chloroketones. The addition is controlled by the reactivity of the chloroketones that allowed the stereoselective reaction to be performed at –20 °C. Chiral racemic chloroketones are used in...

Ausführliche Beschreibung

Bibliographische Detailangaben
Hauptverfasser: Pier Giorgio Cozzi, Diego Petruzziello, Montse Guiteras Capdevila, Enrico Emer, Silvia Alesi, Andrea Gualandi
Format: Artikel
Sprache:English
Veröffentlicht: MDPI AG 2011-06-01
Schriftenreihe:Molecules
Schlagworte:
alkynylation
(R,R)-salen
chloroketones
Me2Zn
phenylacetylene
Online Zugang:http://www.mdpi.com/1420-3049/16/6/5298/

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http://www.mdpi.com/1420-3049/16/6/5298/

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