The Hexacoordinate Si Complex SiCl<sub>4</sub>(4-Azidopyridine)<sub>2</sub>—Crystallographic Characterization of Two Conformers and Probing the Influence of SiCl<sub>4</sub>-Complexation on a Click Reaction with Phenylacetylene

The Hexacoordinate Si Complex SiCl<sub>4</sub>(4-Azidopyridine)<sub>2</sub>—Crystallographic Characterization of Two Conformers and Probing the Influence of SiCl<sub>4</sub>-Complexation on a Click Reaction with Phenylacetylene

4-Azidopyridine (<b>1</b>) and SiCl<sub>4</sub> react with the formation of the hexacoordinate silicon complex SiCl<sub>4</sub>(4-azidopyridine)<sub>2</sub> (<b>2</b>). Upon dissolving in warm chloroform, the complex dissociates into the co...

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Bibliographic Details
Main Authors: Sophie Riedel, Maik Gerwig, Daniela Gerlach, Erica Brendler, Robert Gericke, Edwin Kroke, Jörg Wagler
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Inorganics
Subjects:
chemical shift anisotropy
(3+2)-cycloaddition
Hirshfeld surface analysis
hypercoordination
packing efficiency
polymorphism
Online Access:https://www.mdpi.com/2304-6740/11/12/473

Internet

https://www.mdpi.com/2304-6740/11/12/473

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