New Type-I and Type-II Clathrates in the Systems Cs–Na–Ga–Si, Rb–Na–Ga–Si, and Rb–Na–Zn–Si

Systematic studies in the systems Cs–Na–Ga–Si, Rb–Na–Ga–Si, and Rb–Na–Zn–Si yielded the novel type-I clathrates with refined compositions Cs6Na2Ga8.25Si37.75(3), Rb6.34Na1.66(2)Ga8.02Si37.98(3), and Rb5.20Na2.80(4)Zn3.85Si42.15(2) (cubic, ), as well...

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Bibliographic Details
Main Authors: Marion C. Schäfer, Svilen Bobev
Format: Article
Language:English
Published: MDPI AG 2014-03-01
Series:Inorganics
Subjects:
Online Access:http://www.mdpi.com/2304-6740/2/1/79