Critical Assessment of the Surface Tension determined by the Maximum Pressure Bubble Method

The main factors that influence the value of surface tension of a liquid measured with the Maximum Pressure Bubble Method are critically evaluated. We present experimental results showing the effect of capillary diameter, capillary depth, bubble spheroidicity and liquid density at room temperature....

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Main Authors: Franco Emmanuel Benedetto, Hector Zolotucho, Miguel Oscar Prado
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2015-02-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/pdf/mr/v18n1/1516-1439-mr-18-01-00009.pdf
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author Franco Emmanuel Benedetto
Hector Zolotucho
Miguel Oscar Prado
author_facet Franco Emmanuel Benedetto
Hector Zolotucho
Miguel Oscar Prado
author_sort Franco Emmanuel Benedetto
collection DOAJ
description The main factors that influence the value of surface tension of a liquid measured with the Maximum Pressure Bubble Method are critically evaluated. We present experimental results showing the effect of capillary diameter, capillary depth, bubble spheroidicity and liquid density at room temperature. We show that the decrease of bubble spheroidicity due to increase of capillary immersion depth is not sufficient to explain the deviations found in the measured surface tension values. Thus, we propose a simple experimental procedure that allows determining the surface tension of a liquid without any previous knowledge of its density. This procedure is especially useful when the liquid of interest exhibits variations of surface tension and density with time, as for example during condensation reactions to obtain SiO2 sols from a tetraethyl ortosilicate (TEOS) solutions during their aging process.
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publishDate 2015-02-01
publisher Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)
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spelling doaj.art-bbe06b22064f4a97a280ea5b34776b012022-12-22T04:09:28ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392015-02-0118191410.1590/1516-1439.232513Critical Assessment of the Surface Tension determined by the Maximum Pressure Bubble MethodFranco Emmanuel BenedettoHector ZolotuchoMiguel Oscar PradoThe main factors that influence the value of surface tension of a liquid measured with the Maximum Pressure Bubble Method are critically evaluated. We present experimental results showing the effect of capillary diameter, capillary depth, bubble spheroidicity and liquid density at room temperature. We show that the decrease of bubble spheroidicity due to increase of capillary immersion depth is not sufficient to explain the deviations found in the measured surface tension values. Thus, we propose a simple experimental procedure that allows determining the surface tension of a liquid without any previous knowledge of its density. This procedure is especially useful when the liquid of interest exhibits variations of surface tension and density with time, as for example during condensation reactions to obtain SiO2 sols from a tetraethyl ortosilicate (TEOS) solutions during their aging process.http://www.scielo.br/pdf/mr/v18n1/1516-1439-mr-18-01-00009.pdfsurface tensionMPBMbubble deformationmaximum pressure bubble method
spellingShingle Franco Emmanuel Benedetto
Hector Zolotucho
Miguel Oscar Prado
Critical Assessment of the Surface Tension determined by the Maximum Pressure Bubble Method
Materials Research
surface tension
MPBM
bubble deformation
maximum pressure bubble method
title Critical Assessment of the Surface Tension determined by the Maximum Pressure Bubble Method
title_full Critical Assessment of the Surface Tension determined by the Maximum Pressure Bubble Method
title_fullStr Critical Assessment of the Surface Tension determined by the Maximum Pressure Bubble Method
title_full_unstemmed Critical Assessment of the Surface Tension determined by the Maximum Pressure Bubble Method
title_short Critical Assessment of the Surface Tension determined by the Maximum Pressure Bubble Method
title_sort critical assessment of the surface tension determined by the maximum pressure bubble method
topic surface tension
MPBM
bubble deformation
maximum pressure bubble method
url http://www.scielo.br/pdf/mr/v18n1/1516-1439-mr-18-01-00009.pdf
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AT migueloscarprado criticalassessmentofthesurfacetensiondeterminedbythemaximumpressurebubblemethod