Synthesis, optical properties and crystal structure of (E,E)-1,3-(3,4:9,10-dibenzododeca-1,11-diene-5,7-diyne-1,12-diyl)benzene

Synthesis, optical properties and crystal structure of (E,E)-1,3-(3,4:9,10-dibenzododeca-1,11-diene-5,7-diyne-1,12-diyl)benzene

The dehydrobenzannulene (E,E)-1,3-(3,4:9,10-dibenzododeca-1,11-diene-5,7-diyne-1,12-diyl)benzene, C26H16, was successfully synthesized via photocatalyst-assisted stereoselective reductive desulfonylation of 1,3-bis{1-phenylsulfonyl-2-[2-(trimethylsilylethynyl)phenyl]ethenyl}benzene, C44H42O4S2Si2, a...

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Bibliographic Details
Main Authors: Hikaru Watanabe, Takuma Sato, Michiki Sumita, Mei Shiroyama, Daichi Sugawara, Tomoki Tokuyama, Yasuhiro Okuda, Kan Wakamatsu, Haruo Akashi, Akihiro Orita
Format: Article
Language:English
Published: International Union of Crystallography 2023-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
expanded π-system
dehydrobenzannulene
reductive desulfonylation
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989023006187

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http://scripts.iucr.org/cgi-bin/paper?S2056989023006187

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