Spectrophotometric Study of Adduct Formation Between [Co(Salen)PPh3]ClO4.H2O and [Co(7,7'-Dimethylsalen)PPh3]ClO4.H2O with Amines Donors in Acetonitrile

The equilibrium quotient of the adduct formation of [Co(Salen)PPh3]ClO4.H2O and [Co(7,7'-dimethylSalen)PPh3]ClO4.H2O, as acceptor with amines donors are studied by spectrophotometer. Thermodynamics of these pentacoordinate cobalt(III) Schiff-base complexes have been examined with n-butylamine,...

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Bibliographic Details
Main Authors: Mahmood Niad, Khosro Mohammadi, Mozaffar Asadi
Format: Article
Language:English
Published: Hindawi Limited 2010-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2010/320126