Active Polypropylene-Based Films Incorporating Combined Antioxidants and Antimicrobials: Preparation and Characterization

Development of polypropylene (PP) films incorporating antioxidant-antimicrobial agents can inhibit microbial growth and reduce undesirable deteriorating reactions and can preserve the quality of food. This study was aimed to use a combination of sorbic acid (SA), butylated hydroxyanisole (BHA), and...

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Main Authors: Seyed Hadi Peighambardoust, Seyedeh Homa Fasihnia, Seyed Jamaleddin Peighambardoust, Mirian Pateiro, Rubén Domínguez, José M. Lorenzo
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Foods
Subjects:
Online Access:https://www.mdpi.com/2304-8158/10/4/722
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author Seyed Hadi Peighambardoust
Seyedeh Homa Fasihnia
Seyed Jamaleddin Peighambardoust
Mirian Pateiro
Rubén Domínguez
José M. Lorenzo
author_facet Seyed Hadi Peighambardoust
Seyedeh Homa Fasihnia
Seyed Jamaleddin Peighambardoust
Mirian Pateiro
Rubén Domínguez
José M. Lorenzo
author_sort Seyed Hadi Peighambardoust
collection DOAJ
description Development of polypropylene (PP) films incorporating antioxidant-antimicrobial agents can inhibit microbial growth and reduce undesirable deteriorating reactions and can preserve the quality of food. This study was aimed to use a combination of sorbic acid (SA), butylated hydroxyanisole (BHA), and butylated hydroxytoluene (BHT) to provide a synergistic effect at their reduced concentrations. A Combination of the additives was more effective in enhancing mechanical properties compared to their single state in film composition. The PP-2%SA-3%BHA film (T<sub>3</sub>) had the highest tensile strength (17.9 MPa) and the lowest elongation at break (7.1%) than other films. The fourier-transform infrared (FTIR) proposed physical mixing of active additives within PP-matrix. Scanning electron microscopy showed uniform dispersion of the additives in PP-2%SA-1%BHT-1%BHA film (T<sub>4</sub>) compared to others. BHT containing films decreased the storage and loss moduli leading to weakening of film viscoelastic behaviour and reducing film melting point. The prepared active films showed higher antioxidant activity than control PP-film following an order of T<sub>4</sub> > T<sub>2</sub> > T<sub>3</sub> corresponding to DPPH radical scavenging values of 89.1, 83.4 and 79.1%, respectively. All active films inhibited gram-negative and gram-positive bacteria growth. The results of this study indicated that the prepared active films possess desirable mechanical, thermal, antioxidant and antimicrobial properties enabling their use in food packaging.
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spelling doaj.art-bc5468b82d464ec198d4b4c6112698a92023-11-21T13:18:04ZengMDPI AGFoods2304-81582021-03-0110472210.3390/foods10040722Active Polypropylene-Based Films Incorporating Combined Antioxidants and Antimicrobials: Preparation and CharacterizationSeyed Hadi Peighambardoust0Seyedeh Homa Fasihnia1Seyed Jamaleddin Peighambardoust2Mirian Pateiro3Rubén Domínguez4José M. Lorenzo5Department of Food Science, College of Agriculture, University of Tabriz, Tabriz 5166616471, IranDepartment of Food Science, College of Agriculture, University of Tabriz, Tabriz 5166616471, IranFaculty of Chemical and Petroleum Engineering, University of Tabriz, Tabriz 5166616471, IranCentro Tecnológico de la Carne de Galicia, Rúa Galicia N° 4, Parque Tecnológico de Galicia, San Cibrao das Viñas, 32900 Ourense, SpainCentro Tecnológico de la Carne de Galicia, Rúa Galicia N° 4, Parque Tecnológico de Galicia, San Cibrao das Viñas, 32900 Ourense, SpainCentro Tecnológico de la Carne de Galicia, Rúa Galicia N° 4, Parque Tecnológico de Galicia, San Cibrao das Viñas, 32900 Ourense, SpainDevelopment of polypropylene (PP) films incorporating antioxidant-antimicrobial agents can inhibit microbial growth and reduce undesirable deteriorating reactions and can preserve the quality of food. This study was aimed to use a combination of sorbic acid (SA), butylated hydroxyanisole (BHA), and butylated hydroxytoluene (BHT) to provide a synergistic effect at their reduced concentrations. A Combination of the additives was more effective in enhancing mechanical properties compared to their single state in film composition. The PP-2%SA-3%BHA film (T<sub>3</sub>) had the highest tensile strength (17.9 MPa) and the lowest elongation at break (7.1%) than other films. The fourier-transform infrared (FTIR) proposed physical mixing of active additives within PP-matrix. Scanning electron microscopy showed uniform dispersion of the additives in PP-2%SA-1%BHT-1%BHA film (T<sub>4</sub>) compared to others. BHT containing films decreased the storage and loss moduli leading to weakening of film viscoelastic behaviour and reducing film melting point. The prepared active films showed higher antioxidant activity than control PP-film following an order of T<sub>4</sub> > T<sub>2</sub> > T<sub>3</sub> corresponding to DPPH radical scavenging values of 89.1, 83.4 and 79.1%, respectively. All active films inhibited gram-negative and gram-positive bacteria growth. The results of this study indicated that the prepared active films possess desirable mechanical, thermal, antioxidant and antimicrobial properties enabling their use in food packaging.https://www.mdpi.com/2304-8158/10/4/722active packagingpolypropyleneBHABHTsorbic acidmechanical properties
spellingShingle Seyed Hadi Peighambardoust
Seyedeh Homa Fasihnia
Seyed Jamaleddin Peighambardoust
Mirian Pateiro
Rubén Domínguez
José M. Lorenzo
Active Polypropylene-Based Films Incorporating Combined Antioxidants and Antimicrobials: Preparation and Characterization
Foods
active packaging
polypropylene
BHA
BHT
sorbic acid
mechanical properties
title Active Polypropylene-Based Films Incorporating Combined Antioxidants and Antimicrobials: Preparation and Characterization
title_full Active Polypropylene-Based Films Incorporating Combined Antioxidants and Antimicrobials: Preparation and Characterization
title_fullStr Active Polypropylene-Based Films Incorporating Combined Antioxidants and Antimicrobials: Preparation and Characterization
title_full_unstemmed Active Polypropylene-Based Films Incorporating Combined Antioxidants and Antimicrobials: Preparation and Characterization
title_short Active Polypropylene-Based Films Incorporating Combined Antioxidants and Antimicrobials: Preparation and Characterization
title_sort active polypropylene based films incorporating combined antioxidants and antimicrobials preparation and characterization
topic active packaging
polypropylene
BHA
BHT
sorbic acid
mechanical properties
url https://www.mdpi.com/2304-8158/10/4/722
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AT seyedjamaleddinpeighambardoust activepolypropylenebasedfilmsincorporatingcombinedantioxidantsandantimicrobialspreparationandcharacterization
AT mirianpateiro activepolypropylenebasedfilmsincorporatingcombinedantioxidantsandantimicrobialspreparationandcharacterization
AT rubendominguez activepolypropylenebasedfilmsincorporatingcombinedantioxidantsandantimicrobialspreparationandcharacterization
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