The Use of Anhydrous Barium Hydroxide for Selective Alkylation of Dialkyloxy-<i>tert</i>-butyl-calix[4]arenes

A practical method of selective alkylation of the third hydroxyl group of disubstituted <i>tert</i>-butyl-calix[4]arenes using anhydrous barium hydroxide as a base was developed in this study. The use of this method in the synthesis of inherently chiral derivatives is shown herein.

Podrobná bibliografie
Hlavní autoři: Oleksandr A. Yesypenko, Oleksandr O. Trybrat, Vitaly I. Kalchenko
Médium: Článek
Jazyk:English
Vydáno: MDPI AG 2023-01-01
Edice:Molecules
Témata:
On-line přístup:https://www.mdpi.com/1420-3049/28/3/1089
Popis
Shrnutí:A practical method of selective alkylation of the third hydroxyl group of disubstituted <i>tert</i>-butyl-calix[4]arenes using anhydrous barium hydroxide as a base was developed in this study. The use of this method in the synthesis of inherently chiral derivatives is shown herein.
ISSN:1420-3049