Synthesis of Formate Esters and Formamides Using an Au/TiO2-Catalyzed Aerobic Oxidative Coupling of Paraformaldehyde

A simple method for the synthesis of formate esters and formamides is presented based on the Au/TiO2-catalyzed aerobic oxidative coupling between alcohols or amines and formaldehyde. The suitable form of formaldehyde is paraformaldehyde, as cyclic trimeric 1,3,5-trioxane is inactive. The reaction pr...

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Bibliographic Details
Main Authors: Ioannis Metaxas, Eleni Vasilikogiannaki, Manolis Stratakis
Format: Article
Language:English
Published: MDPI AG 2017-12-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/7/12/440